However, it has a number of limitations in many industrial applications. The

molecular weight of hydrogen is only half that of helium, and hydrogen has a much

higher molecular velocity. As a result, hydrogen diffuses rapidly inside test objects,

and dissipates far more quickly than helium. These properties, and the low price of

hydrogen, make it a very attractive alternative.

There are two main reasons why hydrogen is not already more commonly used than

helium as a tracer gas: a) the perception that hydrogen is too dangerous and b) the

availability of suitable hydrogen detectors.

The flammability problem is easily solved by using a readily available standard mix of

5% hydrogen and 95% nitrogen, which is classified as non-flammable.

The other obstacle was overcome by the introduction of a new type of hydrogen

detector, based on microelectronic hydrogen sensors. These have high sensitivity

and selectivity to hydrogen. Moreover, they are cost-effective and sufficiently robust

5% hydrogen mix. The use of hydrogen as a tracer gas is now increasing rapidly in

the automotive, chemical, power generation, aerospace and telecommunications

industries, among others.

for leak testing. Water baths and foaming agents, for example, are widely employed

in industrial leak location, and are capable of detecting leaks with leak rates down to

both methods are unsuitable for test objects where it is important to avoid exposure

to moisture.

Leak testing often involves the measurement of pressure changes. In industrial

atm cc/s for small-volume test objects. With larger volumes, however, sensitivity

decreases significantly. The accuracy of measurements is also affected by

temperature fluctuations and elastic deformation of test objects. These variables

must therefore be taken into account when determining leak rates. If leak testing by

means of pressure measurement reveals leakage in excess of permissible levels, the

next step is to locate the leak.

The tracer-gas method can be used for both leak location and leak testing. It is also

ideal for locating smaller leaks. Test objects remain dry, and measurements are

unaffected by temperature changes and elasticity. Various tracer gases are currently

used for this purpose. Helium and hydrogen are most common for a wide range of

to use as a tracer gas. It has a very low viscosity and the background concentration

of hydrogen in ambient air is relatively low.

Comparison of the physical properties of hydrogen and helium with those of air:

Hydrogen Helium Air

Dynamic viscosity 8.7 µPas 19.4 µPas 18.3 µPas

Background concentration in air 0.5 ppm 5 ppm 100 %

Mol. mass 2 g/mol 4 g/mol 29 g/mol

amount of tracer gas that escapes through a leak during a defined unit of time

depends on its dynamic viscosity. The background concentration of a tracer gas in

ambient air affects the detection limit.

employed in leak testing. Certified as non-flammable to ISO 10156, this gas presents

no safety risks. It is primarily deployed as a shielding gas for welding, soldering, and

brazing, and is usually provided by industrial gas suppliers in 200 bar (2.900 psi) and

300 bar (4.350 psi) pressurized gas cylinders. The mixture costs a fraction of helium, the

price of which has recently risen sharply due to increased demand. Moreover, as

global resources are finite, helium is expected to become even more expensive. By

contrast, the cost of hydrogen, which is increasingly seen as a source of energy, is

steadily falling.

Unlike helium, hydrogen is a renewable resource, which is an important

consideration for environmental audits under ISO 14001. Furthermore, hydrogen is

non-toxic and non-corrosive.

The physical properties of hydrogen also offer a number of practical benefits.

Hydrogen diffuses much more rapidly than helium, quickly achieving uniform

concentration within the test object. Evacuation of the test object is not generally

required before testing. Moreover, there is far less risk of contamination. In addition,

hydrogen does not adhere to surfaces, and can be flushed out much more rapidly.

The above factors make hydrogen the ideal tracer gas.

However, the hydrogen method requires a testing device with corresponding range

and selectivity (i.e. exclusive to one gas).

The testing device presented here is based on a semiconductor sensor similar in

design to a field-effect transistor. Hydrogen molecules adhere to the surface of the

sensor, where they dissociate into hydrogen ions (protons). These protons can then

penetrate the lattice structure of the sensor, where they cause a change in an

electrical field, triggering a signal that passes along a signal-processing chain to be

displayed by the testing device. The sensor responds selectively to hydrogen. The

detection limit is based on the natural background concentration of hydrogen in air

(0.5 ppm).

To detect a leak, the sensor, which is integrated into the probe, is placed directly

over the leak. This means that no pumps are required to suck gas into the device.

The sensor is linked to the testing device by a single cable. As a result, no filters or

other maintenance-intensive components are needed. A further benefit is that this

direct measurement method has very rapid response times, irrespective of the cable

length, and very short recovery times. The sensitivity of the device can be adjusted

at the touch of a button across a range from 1 to 4,000, depending on the task

involved.

The easy-to-operate, rugged devices are ideal for industrial applications, and can be

quickly and easily calibrated using a reference leak or calibration gas. During

calibration, the current status of the sensor is displayed. A battery- operated version

allows several hours of uninterrupted mobile use.

gas is emitted from the test object. Differential pressure can range from zero to

several thousand bar. Even with absolute differential pressure of zero bar, partial

pressure differential is sufficient to cause hydrogen gas exchange via the leak.

The device is primarily employed to perform leak location or integral leak testing by

known as "sniffing" - which is not strictly accurate here, since tracer gas does not

have to be sucked into the device. With forming gas (95/5), the detection limit is

higher hydrogen concentrations - and corresponding safety measures - or even using

pure hydrogen. Here, the detection limit drops in proportion to the concentration,

enabling lower leakage rates to be detected.

Example applications:

* Leak location on objects of complex shapes.

If a test object (e.g. engine, transmission or axle) has been found to be leaking, the

leaks need to be located as quickly and accurately as possible to enable repairs. The

properties of the tracer gas outlined above and the variable sensitivity of the testing

device enable rapid, straightforward, and precise location of all sizes of leaks. Results

are unaffected by background concentrations of hydrogen. Since tracer gas does not

adhere to surfaces, the effectiveness of repairs can be conclusively verified by

subsequent testing. * High background levels of helium.

Components previously tested using helium are often installed in cooling and airconditioning

systems. As a result, the background concentration of helium at the

assembly site is too high for accurate subsequent measurement. * Rapid leak

location for vacuum systems.

In vacuum systems where there are gross leaks or considerable moisture, leak

location can be extremely time-consuming or impossible. Creating a sufficient

vacuum is a difficult and prolonged process, which the hydrogen method accelerates

significantly. Leak location can begin after the test object has been flushed with

tracer gas described above, results are unaffected by the background concentration

of hydrogen. * Mobile applications In large, complex systems of the kind

encountered in plant engineering, and the chemical and aerospace industries, leak

detection is often extremely time-consuming. Where testing equipment is

insufficiently mobile, and there are background effects due to the tracer gas, the

process can take even longer. The hydrogen leak detection device described above is

available in a battery-powered version for applications of this type. * Hydrogen

systems Systems that run on or contain hydrogen, such as electrolysers, reformers

or even fuel cells, can be tested during operation. This solution is particularly

attractive for regular testing during ongoing operations, where there is a need to

avoid system downtime.

As in leak location, the test object is filled with tracer gas. The increase in the

hydrogen concentration is measured in a known volume created around the test

object. The duration of the test depends on the permissible leakage rate and on the

specific volume involved. Depending on the application, the known volume is created

using either a flexible hood or a solid enclosure.

Example applications

* Systems engineering With heat exchangers and valves, for example, it is important

to check for leaks at the interfaces between individual areas, as well as for external

leaks of the test object. In many cases, overpressure testing involves

significantly less time and effort than vacuum methods. Independent studies verify

that results of equal quality are achieved using both methods. * Volume production

In the automotive industry and refrigeration systems manufacture, components with

low permissible leakage rates are often tested in a vacuum chamber. As a result,

tests performed using this method often involve high capital expenditure and running

costs. In many cases, leak testing can be performed in a simple test chamber at

atmospheric pressure, considerably reducing investment and running costs. *

Research and development In R&D, it is often necessary to determine the leakage

rate of a variety of test objects with a minimum of effort. Measurement using a

flexible hood is particularly suitable. As described above, the tracer gas rapidly

diffuses uniformly within the hood and does not adhere to surfaces, allowing

repeated measurements to be quickly and easily performed. * Car manufacturing

The tightness requirements for fuel systems in cars are becoming ever more

stringent. With conventional fuels, it is increasingly common to measure the total

emissions of the stationary vehicle (zero evap). For hydrogen-powered vehicles, a

simple test of the overall leakage rate of the entire vehicle is required.

Measurements are performed using a hood. * Permeability Testing of permeability is

a specialized application. Forming gas is applied to one side of a material sample,

and the increase in the hydrogen concentration over time is measured on the

opposite side. This procedure is used for packaging materials and membranes.